A Review of the Effect of Different Electrolytes on the Synthesis of Graphene Sheets by Electrochemical Exfoliation

Abstract

Graphene oxide (GO) possess some excellent properties that fulfil various applications. Hummers’ method has been used in GO synthesis for years but some issues such as high-cost GO synthesis, the use of toxic chemicals and low yield of GO are still remains and concerned. In addition, this method spends very long time to be completed and subjected to thorough cleaning process to remove toxic chemicals. On the other hand, the electrochemical method saves time, has no explosion risk, releases no toxic gases, and keep safe environmental. The demand of GO supply is crucial particularly important in applications such as energy storage in automobiles thus, a large scale and cheap production of GO is needed. It is reported that the electrochemical synthesis of GO has more benefits such as rapid synthesis, low cost and environmentally friendly than Hummers’ method, therefore, the impact of different electrolytes is important to be studied.  Herein, various research works about the electrochemical synthesis of GO are reviewed, precisely involving the anodic exfoliation of graphite, exfoliation mechanism and effects of exfoliation parameters.