International Journal of Nanoelectronics and Materials (IJNeaM)

Mutual Coupling Reduction between FSS Decoupling Structure and Nanoantenna Array-Elements in THz Multi-Band Plasmonic UM-MIMO

Ammar Mohammad Issa Banat — 2025-04-09

This study introduces a novel methodology for mitigating mutual coupling in Terahertz (THz) multi-band Ultra-Massive Multiple-Input Multiple-Output (UM-MIMO) systems, specifically focusing on plasmonic nanoantenna arrays. The primary objective is to reduce the interference between Frequency Selective Surface (FSS) decoupling structures and adjacent nanoantenna array elements, which is critical for optimizing THz communication system performance. The research involves the design and characterization of new FSS structures and nanoantenna array geometries, employing advanced materials to enhance mutual coupling reduction. By precisely tuning the array geometry and refining the FSS decoupling structure, the study achieves a significant reduction in mutual coupling, with a frequency offset improvement of 4.7% relative to baseline frequencies. Furthermore, the integration of the optimized nanoantenna array with the FSS structure yields substantial reductions in return loss, with S₁₁ and S₂₂ values reaching approximately -7 dB and -8 dB, respectively. The proposed design also demonstrates a compact and stable configuration, achieving a uniform mutual coupling reduction of approximately -22 dB and FSS decoupling structure. This work provides a robust and efficient solution for enhancing the performance and reliability of multi-band THz UM-MIMO systems.

Determination of mechanical and vibration properties of SiO001, SiO110, SiO111 nanowires using first principles approach

A. Wesam Al-Mufti — 2025-04-16

Nanowires play an important role in various applications, especially in exploring their electronic properties. While their mechanical properties have also demonstrated potential, they have not yet been fully theoretically investigated to determine their specific mechanical properties. The goal of this study is to investigate the mechanical properties of SiO nanowires using density functional theory and a first-principles approach. The mechanical properties along (001), (110), and (111) orientations were examined. The strains of 0.1164 × 10-5, 0.12 × 10-5, and 0.115 × 10-5 for each of the three orientations, with moduli of 149.5 GPa, 75.5 GPa, and 85.1 GPa, were found. The total energies along the same orientations (001), (110), and (111) were found to be -1.33, -1.35, and -1.37 eV, respectively. The corresponding Debye temperatures were 676.14 K, 454.70 K, and 616.26 K. The values of Frantsevich's ratios of 0.38, 0.22, and 0.36 along with Poisson's ratios of 0.33, 0.40, and 0.34 confirmed that the nanowires in all crystal directions are ductile. These results demonstrate that the first-principles approaches utilised in this study to study SiO nanowires' characteristics were able to capture the exact behavior of the nanowire parameters.

A 25 GHz Voltage-controlled oscillator (VCO) for automotive collision avoidance radar

Nazuhusna Khalid — 2025-04-23

This paper presents the design and implementation of a 25 GHz voltage-controlled oscillator (VCO) tailored for automotive collision avoidance radar systems. The VCO, a crucial component of the synthesizer, is essential for generating variable frequencies. This study focuses on addressing the challenges of high-power consumption and phase noise, which are critical factors in the performance of radar systems. The simulations were conducted using LTspice to evaluate the VCO's performance in terms of phase noise and power consumption, utilizing 0.18 µm CMOS technology. The proposed VCO employs a modified current-reuse configuration to enhance power efficiency and incorporates resistive and inductive source degeneration techniques to minimize phase noise. The results demonstrate that the VCO achieves a tuning range of 25.34–25.94 GHz, with an impressive phase noise of -156.61 dBc/Hz at a 1 MHz offset and -157.43 dBc/Hz at a 10 MHz offset for the resistive degeneration configuration. The inductive degeneration configuration shows a phase noise of -156.562 dBc/Hz at a 1 MHz offset and -157.431 dBc/Hz at a 10 MHz offset. Additionally, the power consumption is measured at 207.4 mW for the resistive configuration and 208.39 mW for the inductive configuration. These findings indicate that the proposed VCO design meets the stringent requirements of low power consumption and low phase noise and provides a reliable solution for implementing efficient radar systems in automotive applications.

Characterization of carbon black and graphite filled epoxy conductive ink via green solvent method

Diana Mohamad Kamsani — 2025-04-23

Conductive ink is gaining attention in the electronics industry due to its affordability, simplicity, and environmentally friendly properties. This study aimed to analyze a conductive ink made with Carbon Black (CB) and Graphite (G) as fillers, with epoxy resin as the binder and a green co-solvent of ethanol and distilled water. Various characterization techniques were used to examine the fillers. X-ray diffraction (XRD) revealed that CB exhibited an amorphous region at the (002) peak around 21.1°, while G showed distinct peaks at 26.5° and 54.4°, indicating a well-ordered graphitic structure. UV-Vis analysis showed that both CB and G interacted with the epoxy matrix, with an absorption peak in the 270-280 nm range corresponding to π–π* transitions. Fourier-transform infrared (FTIR) spectroscopy confirmed this interaction, with the presence of hydroxyl groups (2800–3500 cm⁻¹) and carboxyl group vibrations at 1241 cm⁻¹, indicating bonding between the polymer and filler. The dispersion of the fillers in the epoxy matrix was examined using Field Emission Scanning Electron Microscope (FESEM), which also assessed agglomeration. The ink's conductivity was tested according to ASTM F390 standards, with optimal CB loading at 4% achieving a conductivity of 4.49 × 10⁻⁵ S/m and optimal G loading at 3% yielding a conductivity of 7.14 × 10⁻⁵ S/m. These results indicate that G-based conductive ink with 3% loading performs better than CB-based ink for printed electronics applications.

A full range fully analytical drain current model of double gate junctionless field effect transistor with triangle shaped spacer

Anjanmani Baro — 2025-04-23

A full range and fully analytical model for the drain current of a symmetric double gate junctionless field effect transistor with a spacer of triangular shape is presented in the paper. The model is valid in the complete range of operation of the device, i.e., all four modes of operation namely- subthreshold, bulk current, flatband and accumulation modes. The approach to obtain the model is channel resistance based. The resistance of the channel of the device has been obtained from charge enclosed within it. The resistances of the model vary in different modes. Therefore, four expressions are obtained for four different modes of operation namely sub threshold, bulk current, flatband and accumulation. The model is said to be analytical in nature as each mode is represented by one single expression without the involvement of any numerical integration. Quantum confinement effect has also been considered in the model. The model has been validated with the help of simulation results from Technology Computer Aided Design (TCAD) device simulator. For the purpose of validation, the model is compared with simulation results as well as experimental results from existing literature. The average deviation from experimental results is 1.425% and the maximum deviation is 1.7%.

Performance of electrochemical amperometric sensor based on annealed and non-annealed PANI-Ag-Pt nanocomposite thin films for E. coli detection

Huda Abdullah — 2025-04-24

Herein, we report the fabrication of polyaniline with Ag-Pt alloy nanocomposite thin films based amperometric E. coli sensor. The effects of annealing at 300^oC during the synthesis of PANI-Ag-Pt nanocomposite thin films are studied. XRD, AFM, FESEM and FTIR spectroscopy analyses are conducted to characterize the films. Sensor performance is investigated by the I-V characteristic of PANI-Ag-Pt films with and without the presence of E. coli. From XRD analysis, annealed films have larger crystallite sizes than non-annealed films. AFM results indicate that annealed films have lower surface roughness but larger grain size than non-annealed films. FESEM images show Ag-Pt nanorods with sizes of 200-300 nm for non-annealed films and Ag-Pt nanocubes with sizes around 100-550 nm for annealed films. The composition of PANI-Ag_0.2-Pt_0.8 nanocomposite thin film has higher conductivity and performed the maximum sensitivity upon E. coli presence. The sensitivity of annealed PANI-Ag-Pt films is higher than non-annealed PANI-Ag-Pt films.

The influence of midfield applying fly ash for the mechanical arts, and flame resistance of polymer composite

Asra Ali Hussein — 2025-04-24

Polyurethane (PU) grouting material has been widely employed because of its critical function in safeguarding people and property from fires and the burning of polymeric composites. The material's poor flame retardancy and high cost, however, have limited its adoption. Here, in order to reduce the cost of manufacturing and prevent dirt formation from fly ash (FA), we partially replace the conventional filler in PU grouting materials with modified surface fly ash (FA), a byproduct extracted from the ash waste of gas combustion in domestic electric generators in Iraq. The work in this paper includes two types of fillers FA and Zirconium dioxide (ZrO₂). In the first group the surface modified FA(PU/FA) and (PU/ZrO₂). The mixture was prepared separately at 25°C by hand layup method. The second group hybrid composite was prepared, the PU/ZrO₂ at fixed ratio of ZrO₂(1%) were mixed with various loading percent (1%,2%,3%) of FA at room temperature curing also. The composite was characterized using SEM, FTIR and the fire frustration tests included Limited Oxygen Index (L.O.I), maximum flame height, and the moment of ignition time (flame exposure time) and thermal behave hardness of prepared snips using DSC were scrupulous. The outcome expressed that (PU/FA1/Z1) with 1wt.% of each filler had the maximum fire retardancy concluded from weight loss test but at (loading 1%) were obtained the maximum value of hardness (95.4). The fusion was recorded the maximum heat for 1%FA. The final outcomes rating sure on the ability of using faint loadings of prepared FA to mend the fire retardancy, thermal and mechanical properties successfully

Simulation and modeling of gallium nitride high-electron mobility transistors for non-alloyed ohmic contacts

Tung Kok Siong — 2025-04-24

The advantages of gallium nitride (GaN) high-electron mobility transistors, such as concentrated channel electron density, superior electron mobility, and high breakdown voltage, present an opportunity to replace silicon-based devices from modern power conversion systems in the near future. The development of low-resistance ohmic contacts in aluminium gallium nitride (AlGaN)-based GaN devices is crucial for predicting their performance. However, only limited studies have employed technology computer-aided design (TCAD) software to investigate contact resistance in GaN devices and to develop strategies for minimizing contact resistivity. Furthermore, the ohmic contact is able to be achieved only based on different configurations of metal stacks with annealing. This study, using Silvaco TCAD Atlas, first modeled contact resistance in a vertical structure and later extended the study to a lateral structure, which is more feasible for physical manufacturing. The investigation focused on various n++ regions with different doping levels beneath the metal to determine the best optimization for ohmic contact. The result revealed that reducing contact resistivity saturated (1 × 10−6 Ω/cm2) at a thickness of 18 nm for the heavily doped layer (≥ 1 × 1019 cm−3), beyond which no significant decrease in contact resistivity was observed for varying doping levels in n++ layers. This study demonstrates that including a heavily doped layer between the contact and semiconductor surfaces results in the ohmic behaviour emergence in metal contacts.

Optimization of tapered microfiber humidity sensors with molybdenum disulfide coating

Norhafizah Burham — 2025-05-05

This study focuses on developing and optimizing a new optical sensor using tapered microfiber (TMF) for humidity sensing in the 30-80% Relative Humidity (%RH) range. The TMF was fabricated with varying heating lengths (3-6 mm) and waist diameters (3-7 µm), and its performance was tested using a tunable light source and an optical power meter. Results showed that a 5 mm TMF with a 3 µm waist diameter provided the best stability and sensitivity for humidity sensing. Additionally, coating the TMF with Molybdenum Disulfide (MoS2) nanoflakes improved sensitivity by 20-50%, with an error margin of less than 5%. The optimized sensor achieved a sensitivity of -0.244 dB/% and over 97% linearity, demonstrating its potential for precise humidity detection in environmental applications.

Novel composite corn starch-graphene oxide-based polymer electrolyte with the addition of cerium nitrate to improve its ionic conductivity

Nur Laila Hamidah — 2025-05-05

Solid polymer electrolytes (SPE) offer a safer alternative to liquid electrolytes in electrochemical applications, driving interest in enhancing their ionic conductivity. This study examined the impact of adding cerium nitrate (Ce(NO₃)₃) to a composite SPE to boost conductivity. SPEs were synthesized from corn starch, Ce(NO₃)₃ salt, and graphene oxide (GO) via solution casting, using Ce(NO₃)₃ variations of 0%, 2.5%, 5%, 7%, and 9%. X-ray diffraction (XRD) analysis indicated a structural shift toward amorphousness with increasing salt, which enhances ionic mobility. Fourier transform infrared (FTIR) analysis revealed narrowing of the O-H peak with starch and GO, implying hydrogen bonding that promotes an amorphous phase. At the CH₂OH peak, salt addition suggested interaction with starch. Scanning electron microscopy (SEM) showed a porous composite morphology conducive to ion movement. Thermogravimetric analysis (TGA) confirmed good thermal stability. Electrochemical impedance spectrometry (EIS) results showed an increase in ionic conductivity in SPE due to the addition of Ce(NO₃)₃ with the highest conductivity value observed at the 9% variation, reaching 39 times higher than those without Ce(NO₃)₃. This study highlights significant improvements in ionic conductivity by incorporating Ce(NO₃)₃ into SPE, enhancing the energy storage system’s performance. The research offers valuable insights into developing advanced SPE materials with superior electrochemical properties for further exploration and innovation in the field of electrochemical devices.

Graphene-enhanced surface plasmon resonance in photonic crystal fiber for sensing glucose in serum

Malik J. Abd-ALhussain — 2025-05-05

This study presents a solid-core photonic crystal fibre (PCF) with a metallic nanolayer of gold (Au)/silver (Ag) and graphene on the outer surface for glucose sensing applications. Graphene nanoparticles were prepared by pulsed laser ablation in liquid (PLAL) and then mixed with a polyvinyl alcohol (PVA) solution to coat the PCF surface. Glucose solutions with a refractive index (RI) ranging from 1.3475 to 1.3502 were used for evaluation. Results exhibit that the PCF sensor's sensitivity is significantly improved by incorporating a graphene layer onto the Au/Ag nanofilm coatings. The maximum sensitivity achieved for glucose detection in blood was 4284.243 nm/RIU and 3775 nm/RIU, with corresponding resolutions of 1×10-5 and 1.5×10-5 for graphene on Au and Ag, respectively. Experimental values yielded sensitivities of 1314 nm/RIU and 1119 nm/RIU, with resolutions of 2.5×10-5 and 2.7×10-5 for graphene on Au and Ag, respectively. Nanomaterials were investigated using a multi-technique approach encompassing transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), Raman spectroscopy, and UV-VIS spectroscopy. TEM provided nanoscale visualization, revealing size, shape, and distribution characteristics. FTIR spectroscopy identified functional groups and bonding features, sp2 C-C bond stretching between 1580 and 1450 cm-1. Raman spectroscopy assessed structural integrity via D and G bands at 1350 cm-1 and 1590 cm-1. UV-vis spectroscopy elucidated optical properties. Integrating metallic Au/Ag and graphene layers on the PCF exterior shows excellent potential for developing susceptible bio-chemical detection devices.

Optical properties of Al2O3 thin film deposited by pulsed laser deposition technique

Abeer R. Abbas — 2025-05-05

An aluminum oxide (Al2O3) thin film has been grown on a quartz substrate by the pulsed laser deposition (PLD) technique at room temperature under a vacuum pressure of 10–2m bar at different laser wavelengths (1064 nm, 532 nm, and 355 nm). The optical properties concerning the absorption, transmission spectra, and energy gap were studied for the prepared thin film due to UV-visible spectrometer at room temperature with wavelength range (200-1000 nm). The absorption peak is 197 nm at wavelength 1064 nm, 196 nm at wavelength 532 nm, and 195 nm at wavelength 355 nm. The optical energy gap is an essential parameter for investigating thin films' properties. The value of the direct energy gap (Eg) for the prepared films was derived from the graph relationship between
(ℎʋ h) and the energy gap (αhν)2 values for the various wavelengths (4.5 eV at 1064 nm, 5.1 eV at 532 nm, and 5.5 eV at 355nm), indicating the potential use of the thin film as gas sensors.

Effect of laser wavelength on Indium Trioxide (In2O3) thin films deposited by pulsed laser deposition method

Sarah M. Taleb — 2025-05-05

The pulse laser deposition (PLD) technique was used to prepare and deposit indium trioxide (In2O3) as thin films with a nanocrystalline structure on the silicon porous and quartz substrates. The laser wavelength effect on the optical and structure properties of these films was investigated. The PLD technique is accomplished using the following constant parameters: temperature (300°C), frequency (3 Hz), number of pulses (250 pulses), and voltage (900 V), but with three different laser wavelengths: 1064 nm, 532nm, and 355nm. To characterize and analyze these nanostructure thin films Ultra-Violet Visible (UV-vis) and X-ray diffraction (XRD) were used. The UV-vis analysis shows that: the laser wavelength does not have a significant effect on the transmission, absorption, and energy band gap values, it can be seen that when the laser wavelength increases the transmission values of thin films increase. While the values of absorption and energy band gap appear the random behavior with this increase. Also, it can be noted the laser wavelength does not have a significant effect on the refractive index values, since it achieves close values when the three different laser wavelengths were used. The XRD analysis shows that: the structure of In2O3 thin film will be purer and more crystalline with increasing laser wavelength because the intensity of phase 2θ at values of 31.8°, 34.06° and 63.48° correspond to (222), (400), and (662) planes increased when the laser wavelength increases.

Selectivity study towards 17α-ethinylestradiol (EE2) detection based on silica microsphere-gold nanoparticle

Nur Hamidah Abdul Halim — 2025-05-08

The widespread use of 17α-Ethinylestradiol (EE2), a synthetic estrogen female hormone with potent physiological effects at lower concentrations than other steroids, poses environmental and health concerns due to its weak electrochemical behavior. Current detection methods lack the requisite sensitivity and selectivity for precise EE2 monitoring, posing potential risks in diverse environments. A critical need exists for a high-performance electrochemical biosensor to address these limitations and selectively detect EE2 with enhanced sensitivity. This development is crucial for accurate monitoring and risk assessment in the context of EE2 exposure. Silica nanoparticles offer advantageous features such as high surface area, excellent stability, large pore volume, adjustable shape, and size, simplicity of production, and biocompatibility. Additionally, gold nanoparticles are effective in facilitating electron transfer processes. Characterization through cyclic voltammogram (CV) and differential pulse voltammogram (DPV) revealed that the anodic peak current of electrodes modified with both silica and gold surpasses that of electrodes modified with silica or gold alone. Notably, the anodic peak current exhibits an upward trend with increasing concentrations of EE2, emphasizing the heightened sensitivity achieved through the incorporation of silica and gold in the electrode modification. The current of the anodic peak was linear within the range 110-6 -110-4 M EE2 concentration with linear regression equation Ipa (A) = 1.639CEE2 + 120.55 and R2=0.939. It may be seen that the electrochemical biosensor is superior in performance, due to the presence of the silica and gold that provides sensitivity for EE2 detection. Furthermore, in terms of selectivity, it was found that this sensor possessed acceptable performance in terms of selectivity through E3 which gained an overall percentage change of 0.04%, while E2 gained an overall percentage change of 10.23%, which is considered a good selectivity specifically for E3. The incorporation of silica and gold nanoparticles in electrode modification resulted in a noteworthy outcome: the anodic peak current surpassed that of electrodes modified with silica or gold alone. This increase in current intensity exhibited a direct correlation with the rise in concentrations of EE2, highlighting the enhanced sensitivity achieved through the synergistic combination of silica and gold nanoparticles.

Fabrication and characterization of nanoporous diatomaceous earth on silicon substrate

A.Wesam Al-Mufti — 2025-05-20

Nanoporous materials have gained significant attention for their unique structural properties and potential applications in various fields. This study focuses on the fabrication and characterization of diatomaceous earth on a silicon substrate. The SEM micrographs of diatomite reveal mass holes distributed over its surface with pore diameters ranging from 0.25 to 0.70 µm, classifying it as macroporous. Locally magnified images (30,000x) demonstrate subcircular pores with diameters around 470 nm. Pore size distribution, analyzed using diatomite-based ceramics and silver (II) oxide-draped porous composite ceramics through the mercury intrusion technique, indicates that diatomite-based porous ceramics have pore sizes between 0.675 and 40 µm, with a majority of pores having similar dimensions. High-temperature calcination (950°C) resulted in the melting and fusion of diatomite material pores, leading to broken pore structures. Following silver (II) oxide deposition, the composite ceramics exhibited pore sizes ranging from 0.017 to 5 µm and 5 to 21 µm, with most pores measuring approximately 3 µm and 11 µm, respectively. These findings contribute to the understanding of nanoporous material behavior

Application of the extracted microcrystalline cellulose from pineapple leaf fibers for wound dressing materials

Dania Khoirun Nisa — 2025-05-20

The wound healing process involves replacing damaged tissue through a series of cellular events. Microtechnology has the potential to provide the specific physicochemical properties and biological responses necessary to facilitate and support the wound healing process. Many natural biopolymers have been developed in the design of wound dressings. Hydroxyapatite and collagen exhibit antibacterial effects, anti-inflammatory and hydrophilic properties that can support wound treatment and prevent infection. Meanwhile, cellulose has been developed a lot regarding the utilization of its mechanical properties. This research aims to analyze the effect of variations in microcrystalline cellulose (MCC) composition on the physical and mechanical properties of HA/collagen composite scaffolds. The samples obtained were characterized by XRD, SEM, EDS, and UTM. The cellulose sample showed a diffraction peak at 21.7°, which increased significantly in the MCC spectrum. The intensity value was higher after going through the hydrolysis process, indicating that the hydrolysis process was able to increase the MCC intensity with a crystallinity index reaching 70.2%. The addition of MCC in the HA/collagen composite scaffold had an impact on increasing the strain value by 63.77% and relatively reducing the fiber diameter and membrane porosity.

Improvement of corrosion resistance of Ti13Nb13Zr alloy using biomedical nanoceramic coatings

Abbas Al-Bawee — 2025-05-20

Metals used for mending fractures or substituting implants due to osteoporosis or injuries need to possess strength, durability, and compatibility with living tissue. For instance, titanium metal exhibits exceptional antibacterial attributes and has brought about enhanced biocompatibility and osseointegration. Titanium-based biominerals may exhibit specific biological functions through their nanoscale coating. The coating process involved electrophoretic deposition and then sintering at 400 °C. The samples were analyzed using XRD, FE-SEM, OCP, and Tafel electrochemical corrosion cell. The treated samples exhibited significantly greater resistance to corrosion compared to their untreated counterparts. The corrosion rate went from 15.13 × 10-5 mmpy for the uncoated sample to 9.564 × 10-6 mmpy for the coated sample by HA70MgO15YSZ15 and then to 4.683 × 10-6 mmpy for the coated sample by HA70MgO15(Al2O3)15 and finally to 2.522 × 10-6 mmpy for the sample coated sample HA55MgO15YSZ15 Al2O315. The coated samples showed an increase in open circuit potential and a significant decrease in contact angle from 73.848° to 4.513°, indicating improved biocompatibility of medical titanium alloys.

Comparative analysis of the efficacy of bulk and membrane nanoporous materials in biological sensing

Shahidah Arina Shamsuddin — 2025-05-20

Nanoporous materials possess significant potential in biological sensing applications due to their unique pore structures and high surface-area-to-volume ratios. Two common types of nanoporous materials are bulk and membrane-based. The differences in the structural and dimensional properties of nanopores are expected to impact the efficiency of biomolecule interactions during immobilization and hybridization, thereby influencing the overall performance of biological sensors. This study aims to investigate which type of nanoporous material offers enhanced sensitivity in detecting DNA targets. In this context, activated rice husk carbon (ARHC) and anodic aluminum oxide (AAO) were used to represent bulk and membrane nanoporous materials, respectively. Chitosan was mixed with ARHC to improve conductivity and provide better adhesion to the electrode substrate. ARHC and AAO thin films were characterized using SEM, XRD, and FTIR. Their performance in biological sensing was evaluated using Electrochemical Impedance Spectroscopy (EIS). Compared to chitosan/ARHC, the charge transfer resistance (Rct) at the AAO/electrolyte interfaces was three times higher due to the smaller pore size and narrow, long nanoporous tunnel structure. Consequently, the sensitivity of the AAO thin film electrode in detecting DNA hybridization was lower (0.1312 Ω·M⁻¹) compared to the chitosan/ARHC electrode (0.0343 Ω·M⁻¹), which has a larger pore size and interconnected nanopore structures. The limit of detection (LOD) was also affected, with the AAO thin film electrode exhibiting a higher LOD of 3.0 × 10⁻¹³ M, while the chitosan/ARHC electrode demonstrated a lower and better LOD of 8.0 × 10⁻²⁵ M. This study demonstrates that the type of nanoporous material significantly impacts sensitivity performance in biological sensing.

Reduction of reduced graphene oxide from synthetic graphite produced from oil palm trunk waste

N. A. Karim — 2025-05-20

Graphene has received great attention in various fields, including energy storage, electronics, gas sorption, separation, sensing, and catalysis fields due to its exceptional thermal, electrical, magnetic, optical, and mechanical capabilities as well as its substantial specific surface area. However, this super great graphene is derived from precursor materials, primarily graphite. Synthetic graphite produced from oil palm trunk (OPT) waste has been reported to have excellent chemical properties that are comparable to those of commercial graphite. Through the synthetic graphite from oil palm trunk (OPT) waste, graphene oxide (GO) can be obtained via the modified Hummers' method. The as-produced GO can be reduced to form reduced graphene oxide (RGO) through various processes such as thermal and chemical reduction. In this study, GO that was obtained from synthetic graphite via the modified Hummers' method undergoes chemical reduction to produce RGO. Sodium borohydride (NaBH4) is used as the reducing agent in the chemical reduction. The RGO produced by the chemical reduction is expected to show all the characteristics comparable to those of RGO produced from commercial graphite. X-ray diffraction (XRD) analysis reveals a peak at 26° (2Ɵ) for all graphene oxide samples. RAMAN spectroscopy confirms the graphitic nature of the produced RGO, with observed D, G, and 2D peaks. Additionally, Fourier-transform infrared (FTIR) spectroscopy indicates the presence of functional groups such as amine, phenol, alkene, and alcohol in the RGO produced from synthetic graphite, demonstrating its similarity to RGO derived from commercial graphite.

Synthesis of In2O3 nanoparticles decorated multi-walled carbon nanotubes by laser ablation in liquid and their characterization

Hawraa M. Abdul-Redaa — 2025-05-20

Here, we report the application of the pulsed Nd: YAG-laser ablation technique (PLA) to the decoration of In2O3 nanoparticles (NPs) on Multi-Wall Carbon Nanotubes (MWCNTs). Nanocrystalline indium oxide particles were prepared for the first time by direct interaction of indium target with different laser energy for 100 pulses. We could regulate how much the nanoparticles covered the MWCNTs surface by applying the number of laser ablation pulses 50, 75, 100, and 125 at 550 mJ. A Q-switched Nd: YAG laser (1064 nm) with a 9 ns pulse width was used to accomplish the ablation process. The absorption spectra of the pure In2O3 NPs and decorated nanotubes showed a prominent peak at about 275 nm and 265 nm, respectively. It is discovered that the band energy of the prepared samples is laser parameters dependent. It was decreased with increasing the laser energy for pure In2O3 NPs and decreased with increased laser shots for In2O3@MWCNTs nanostructure. X-ray diffraction analysis demonstrated the presence of CNTs and In2O3 nanoparticles phases. The Photoluminescence spectra (PL) peak emission of In2O3@MWCNTs nanostructure was in the visible region and lower intense than that of In2O3 nanoparticles. Energy-dispersive spectra showed the presence of C, O, and indium in the final product. The results showed that adding In2O3 NPs to the surface of MWCNTs is a viable way to improve wideband light absorption. This approach also offers more effective charge transfer with the lowest effective recombination rate, which improves photocatalytic performance and may find use in optoelectronic devices.